



What Glass Is: Structure and Compositions
Article 01 / 15
15 min de lecture
Before the flame, the material. Glass is rigid and fragile all at once, made of sand and born of fire. This first entry begins smaller than the material, with the atoms glass is made of and why they join, then looks at what glass actually is, at the main glass compositions and how they combine.
Before glass: atoms and the need for balance
Inside an atom
Everything glass is made of, the sand, the soda, the boron, the metals that colour it, is made of atoms. An atom has a tiny, heavy centre, the nucleus, built from two kinds of particle: protons, which carry a positive charge, and neutrons, which carry none. Around the nucleus move electrons, far lighter and negatively charged.
- Protons decide what an element is. Every atom with 8 protons is oxygen, every atom with 14 is silicon, 5 is boron, 27 is cobalt.
- Neutrons add mass and help hold the nucleus together. Atoms of the same element with different numbers of neutrons are called isotopes; chemically they behave almost the same.
- Electrons decide how an atom behaves: which other atoms it joins, how strongly, and how it meets light.
A neutral atom has as many electrons as protons, so the charges cancel out. The electrons are arranged in shells around the nucleus, and only the outermost one, the valence shell, takes part in bonding.
Why atoms join
Atoms are most stable when their outer shell is complete, which for the lighter elements in glass means eight electrons. Very few atoms are born that way. The noble gases, such as neon and argon, are, and that is why they hardly react with anything. Every other atom is, in a sense, out of balance, and it finds balance by giving, taking or sharing electrons with its neighbours. That exchange is a chemical bond.
- Sharing (covalent bonds): two atoms each contribute electrons to a shared pair that belongs to both. Silicon has four outer electrons and oxygen six; by sharing, they hold each other tightly.
- Giving and taking (ionic bonds): some atoms let go of their outer electrons easily, such as sodium, potassium and calcium; others pull electrons in, above all oxygen. An atom that has lost electrons becomes a positive ion, one that has gained them a negative ion, and opposite charges attract.
Most real bonds sit somewhere between the two. The bond between silicon and oxygen is partly shared and partly ionic, and it is one of the strongest in the minerals of the earth's crust.
From atoms to glass
This search for balance is what builds glass. Each silicon atom bonds to four oxygens, and each oxygen can bridge two silicons, so the atoms link into the continuous network described below. Sodium and calcium, added as fluxes, give their outer electrons to oxygen and become positive ions: they break some of the oxygen bridges and settle in the gaps, held by attraction rather than by shared electrons. Fewer bridges means a network that softens at a lower temperature. Boron, with three outer electrons, joins the network in its own way, building units of a different shape.
It is also why glass takes colour. A metal such as cobalt, copper or iron enters the glass as an ion, having given some of its electrons to oxygen. How many it has given is its oxidation state, and the electrons it keeps sit at particular energy levels. When light passes through, those electrons absorb the colours whose energy matches the gap between levels and let the rest through. Change the number of electrons, with a flame rich in oxygen or rich in fuel, and the colour changes too: copper as Cu²⁺ is turquoise, while copper reduced to neutral atoms that cluster into tiny particles turns ruby red. Oxidation is exactly this: electrons moving from one atom to another. Colour in Glass follows it metal by metal.
An amorphous solid
Structure
Glass is made from sands with a high silica content (SiO2), the same compound that forms the mineral quartz. But even though glass is made from the same chemical compound as quartz, its internal structure is very different:
glass is an amorphous solid.
This means it is solid, but its atoms are not arranged in a repeating pattern. That structure is decided as the hot liquid cools and stiffens:
- Crystallisation: the atoms organise themselves into a regular, repeating pattern. Examples: salt, quartz, diamond.
- Disordered freezing: the atoms stay connected, but without a regular pattern. This happens when cooling stops the atoms from organising: they don't have time to rearrange and are left in a disordered structure. The bonds still exist, just without a pattern. Example: glass.
Glass is not simply "quickly cooled quartz". Glass recipes include ingredients that make crystallisation harder. Sodium and calcium break up the silica network; boron joins the network but builds it from units of a different shape. Either way the network loses its symmetry, a regular pattern becomes harder to form, and the glass prefers to stay amorphous.
When a rod of borosilicate is heated in the flame, the bonds in this network break and re-form faster and faster, and the glass flows: it becomes a thick liquid, just as disordered as the solid. As it cools, the movement slows until the disorder is frozen in place, and it is an amorphous solid once more.
I like to think of her as someone who almost reaches where she wants to be; but ran out of time. Like who arrives late everywhere, misses the last train, misses the deadline, dies trying. She embraces her own lateness, but forgives that delay in no one but herself. Passing through skins. A container of fluids. Able to hold.
Composition
The main component of most glass is silicon dioxide. As we saw above, each silicon atom bonds to four oxygen atoms, forming a small pyramid called a tetrahedron, and the tetrahedra share their corners to build a three-dimensional network. This network is extremely strong, which is why pure silica only melts above about 1,700 °C (3,090 °F). Glassmakers add other oxides, in three families:
- Network formers build the network: silica (SiO2), boron oxide (B2O3), phosphorus pentoxide (P2O5).
- Network modifiers partly break the network and lower the melting temperature: sodium (Na2O), potassium (K2O), calcium (CaO).
- Intermediates, such as alumina (Al2O3), strengthen the network and improve its resistance to water and chemicals.
Where modifiers break the network, they leave a more open, irregular structure, and that openness is what lets glass take in other elements, including the metals that colour it. Glass, then, is a disordered network that can "trap" atoms, ions or particles in different forms. That allows it to:
- dissolve metals as ions → transparent colours
- form tiny metal particles → intense colours
- form tiny crystals → opacity
How each of these works is the subject of Colour in Glass.
Devitrification
Glass can crystallise if it is kept hot for too long, or if it contains impurities that act as seeds for crystals. Time plus temperature gives the atoms the chance to reorganise: exactly the opposite of what makes glass. This is called devitrification, and small crystals form, usually on the surface. Glassworkers call it devit. It shows as a dull, frosty skin that will not melt smooth, and it weakens the glass.
At the torch, the usual causes are working one area for too long, reheating it again and again, and dirt or residue on the rod. Clean glass and efficient heating are the best prevention. Some colours are more prone to devit than others.
Solid, liquid, or something in between?
The glass transition
A crystal such as ice has a sharp melting point: at 0 °C it is solid, a moment later it is water. Glass has no single melting point. As it cools from a melt, it simply becomes stiffer and stiffer. This stiffness is its viscosity, its resistance to flow, and it rises by many orders of magnitude between the runny melt and the rigid rod.
Glass-forming melts are cooled past the point where they "should" crystallise without doing so. For a while they are a supercooled liquid: still able to flow and rearrange. Keep cooling, and the atoms eventually move so slowly that their arrangement is fixed. The temperature region where this happens is the glass transition, written Tg. Below it, the material is a glass: a solid with the frozen-in disorder of a liquid.
The glass transition is a range rather than a sharp line, and it shifts a little with how fast the glass cools. For laboratory borosilicate it lies around 525 °C. It sits close to the annealing range, where a finished piece is held in a kiln so the stresses frozen in during working can relax before it cools slowly to room temperature. Annealing is covered in Finishing, Combining and Troubleshooting.
The myth of flowing windows
A well-known story says that glass is "really a liquid", and that old church windows are thicker at the bottom because the glass has flowed down over the centuries. It is not true.
- At room temperature, glass is far below its glass transition. Researchers at Corning measured the viscosity of medieval glass from Westminster Abbey and calculated that it would flow by around a nanometre in a billion years.
- The uneven panes come from how they were made. Much early window glass was blown and spun into a flat disc that was thicker at the centre than at the edge, so the panes cut from it varied in thickness, and glaziers tended to set the heavier edge at the bottom.
- If glass flowed, ancient Roman glass would have slumped out of shape long ago. It hasn't.
Glass is best described as an amorphous solid: rigid like a solid, disordered like a liquid.
Glass compositions and compatibility
Glass rods and tubes come in many colours and sizes. If you are starting out, begin with clear or single-colour rods to learn the basic techniques. These are the main glass compositions and what they are used for:
- Soda-lime glass (roughly 70–74% SiO2, with Na2O and CaO). The most common glass: bottles, jars and windows. Cheap and easy to melt, but it expands a lot when heated, so it cracks easily under sudden temperature changes, and it is less chemically durable than borosilicate.
- Soft glass is the lampworkers' name for soda-lime-type glass made for the torch, such as the Italian rods sold as Effetre or Moretti (COE about 104). It becomes workable at lower temperatures than borosilicate (Effetre's listed working temperature is about 945 °C, 1,733 °F), and metals dissolve in it easily, so its colour range is very wide. It is prone to thermal shock and must be warmed into the flame gradually. Often used for beads. Kiln-fusing glass is a related family, sold in matched ranges such as COE 90 and COE 96.
- Borosilicate (about 80% SiO2, 13% B2O3, 4% Na2O, 2% Al2O3). Boron oxide replaces much of the soda and lime, giving a tight network with very low thermal expansion, so it resists thermal shock and chemical attack. Used for laboratory glassware, ovenware, sculpture and jewelry. It is the glass of all Rain and Rivers jewelry.
- Lead glass (SiO2 with lead oxide, PbO). Lead raises the refractive index, so the glass sparkles, and makes it easier to cut and engrave. This is the glass of traditional "crystal" wine glasses: in the European Union, "lead crystal" must contain at least 24% PbO. When we call a glass "crystal", it doesn't mean it has an ordered atomic structure; the name is historical.
- Aluminosilicate glass (SiO2 with a high proportion of Al2O3). Very strong and heat resistant. Most phone cover glass is an alkali-aluminosilicate that is chemically strengthened: in a bath of molten potassium salt, larger potassium ions replace smaller sodium ions at the surface, squeezing it into compression that resists cracks.
- Pure silica glass, or fused silica (SiO2 alone). The lowest expansion of the common glasses, and extremely heat resistant. Used in optics and science.
- Phosphate glass (built on P2O5 rather than silica). Doped with neodymium, it is used in high-power lasers.
- Fluoride and chalcogenide glasses (fluorides, or sulphur, selenium and tellurium, instead of oxides). Used for infrared: special optical fibres and thermal-imaging lenses.
Compatibility
Every glass expands as it heats and contracts as it cools, and each composition does so by a different amount. If two glasses joined together contract differently, one pulls against the other: internal stress, and sooner or later a crack, sometimes at the torch, sometimes days later.
This movement is measured as the coefficient of thermal expansion, COE. "COE 33" is shorthand: the glass grows by 33 × 10−7 of its length for every degree Celsius (measured between 20 and 300 °C). Data sheets write the same value as 3.3 × 10−6 per kelvin. The lower the number, the less the glass moves and the better it survives sudden temperature changes.
| Glass | Typical COE (× 10−7/°C) | Where you meet it |
|---|---|---|
| Fused silica | about 5 | Optics, laboratory ware |
| Borosilicate | 32–33 | Laboratory glass, ovenware, flameworked sculpture and jewelry |
| Window and bottle glass | about 85–90 | Everyday soda-lime glass |
| Fusing glass | 90 or 96 | Kiln-formed glass |
| Italian soft glass (Effetre/Moretti) | about 104 | Lampworked beads |
The practical "rules" follow from this:
- Never mix glasses from different COE families. Boro and soft glass will not stay together, and neither will COE 90 and COE 96 fusing glass. Which although a "rule", my practice is very much experimental, and I enjoy encapsulating glass to see what happens.
- Within a family, use rods, colours, frit and stringer sold for that system. For borosilicate, that means colours made to be compatible with COE 33 clear.
- A matching number is a strong guide, not a guarantee: glasses also differ in viscosity, so even two glasses sold as the same COE can occasionally disagree. "Tested compatible" ranges have been checked by the manufacturer.
How to test compatibility
- The stringer (pull) test. Melt the tips of two rods together side by side, pull the joined glass into a thin thread and let it cool. If the thread stays straight, the glasses agree. If it curves, they don't: the stronger the curve, the bigger the mismatch.
- The polariscope. Join a small test piece to clear glass of your system, anneal it, and look at it between two crossed polarising filters with light behind. Stress shows as bright halos around the joint; a compatible, well-annealed piece looks calm. The same check tells you whether a finished piece was properly annealed.
Understanding borosilicate
Borosilicate is a favourite among professional flameworkers for intricate, robust pieces. Its history, from Otto Schott's laboratory in Jena to the studio, is told in A History of Glass and Lampworking.
High thermal resistance
Borosilicate has a low coefficient of thermal expansion (COE 33), about a third of that of soft glass, which makes it resistant to thermal shock. It can go in and out of the flame, with thick and thin areas side by side, without cracking at once, so you can work on larger or more complex pieces. It also needs more heat to be shaped. Laboratory borosilicate data sheets give these reference points:
| Point | Temperature | What it means |
|---|---|---|
| Working point | about 1,260 °C (2,300 °F) | Soft enough to shape and blow |
| Softening point | about 825 °C (1,515 °F) | Begins to sag under its own weight |
| Annealing point | about 560 °C (1,040 °F) | Internal stress relaxes within minutes |
| Glass transition | about 525 °C (980 °F) | Below this, the structure is frozen |
Coloured rods vary slightly, so follow the annealing schedule your glass supplier recommends. Boro is normally worked on a torch fed with fuel gas and oxygen, which brings its own safety requirements: see The Studio.
Working with precision
Because borosilicate tolerates repeated heating and is stiffer than soft glass when hot, thin sections hold their shape where you put them. It moves more slowly, so it rewards patience and precise torch control. This suits thin, intricate structures such as twisted cane and delicate hollow forms, and jewelry that has to be worn every day.
Why borosilicate suits jewelry
- Thermal shock resistance. A pendant can go from a warm hand to cold air without cracking.
- Chemical durability. It resists water, sweat, soap and most everyday chemicals, so its surface stays clear and bright.
- Strength in thin forms. Properly annealed, it makes fine, light pieces that are robust for their size. It is still glass, though: a fall onto stone can break it. She asks for care.
Colours and frits
When combining glasses or adding colour, always consider the COE to prevent stress fractures. Borosilicate works only with colours and frits designed for it, so choose materials made for COE 33, and test unfamiliar colours before using them in a finished piece.
Now that we know what glass is, the next entry follows its long story, from the first beads of Mesopotamia to the torch: A History of Glass and Lampworking.
Testez-vous10 questions
Choisissez une réponse pour chaque question, puis vérifiez vos résultats à la fin.
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01What kind of solid is glass?
Its atoms are bonded together but not arranged in a repeating pattern: the disorder of a liquid, frozen in place.
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02What is the main component of most glass?
Silica forms a network of linked tetrahedra. It is the same compound that forms quartz, arranged without order.
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03Why do glassmakers add network modifiers such as sodium and calcium?
Pure silica only melts above about 1,700 °C. Modifiers open up the network so the glass melts and works at lower temperatures.
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04What is devitrification?
Too much time at heat, or dirt on the rod, lets crystals start to grow. Glassworkers call it devit.
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05Why are some old church windows thicker at the bottom?
At room temperature glass is far below its glass transition. Medieval glass would flow about a nanometre in a billion years.
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06What is the typical COE of borosilicate glass?
COE 33 means it grows 33 × 10⁻⁷ of its length per °C: about a third of soft glass, which is why it resists thermal shock.
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07What happens when two glasses with very different COE are fused?
One glass pulls against the other as it shrinks. Annealing cannot fix a mismatch in expansion.
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08What is "soft glass" in lampworking?
Soft glass works at lower temperatures and has a wide colour range, but it expands far more than borosilicate.
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09In the stringer pull test, what does a curved thread tell you?
A straight thread means the glasses agree. The stronger the curve, the bigger the mismatch.
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10Which pair of qualities makes borosilicate well suited to jewelry?
It survives temperature changes and resists water, sweat and soap. It is still glass, though: she asks for care.
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